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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Particle in a one-dimensional lattice ： ウィキペディア英語版 Particle in a one-dimensional lattice In quantum mechanics, the particle in a one-dimensional lattice is a problem that occurs in the model of a periodic crystal lattice. The potential is caused by ions in the periodic structure of the crystal creating an electromagnetic field so electrons are subject to a regular potential inside the lattice. This is an extension of the free electron model that assumes zero potential inside the lattice. ==Problem definition== When talking about solid materials, the discussion is mainly around crystals - periodic lattices. Here we will discuss a 1D lattice of positive ions. Assuming the spacing between two ions is , the potential in the lattice will look something like this: The mathematical representation of the potential is a periodic function with a period . According to Bloch's theorem, the wavefunction solution of the Schrödinger equation when the potential is periodic, can be written as: :$\backslash psi\; (x)\; =\; e^\; u(x).$ Where is a periodic function which satisfies . When nearing the edges of the lattice, there are problems with the boundary condition. Therefore, we can represent the ion lattice as a ring following the Born-von Karman boundary conditions. If is the length of the lattice so that , then the number of ions in the lattice is so big, that when considering one ion, its surrounding is almost linear, and the wavefunction of the electron is unchanged. So now, instead of two boundary conditions we get one circular boundary condition: :$\backslash psi\; (0)=\backslash psi\; (L).$ If is the number of Ions in the lattice, then we have the relation: . Replacing in the boundary condition and applying Bloch's theorem will result in a quantization for : :$\backslash psi\; (0)\; =\; e^\; u(0)\; =\; e^\; u(L)\; =\; \backslash psi\; (L)$ :$u(0)\; =\; e^\; u(L)=e^\; u(N\; a)\; \backslash to\; e^\; =\; 1$ :$\backslash Rightarrow\; kL\; =\; 2\backslash pi\; n\; \backslash to\; k\; =\; n\; \backslash qquad\; \backslash left(\; n=0,\; \backslash pm\; 1,\; \backslash cdots,\; \backslash pm\; \backslash right).$ 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Particle in a one-dimensional lattice」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.